电热蒸发进样微波诱导等离子体原子吸收光谱法测定银和镉的研究

研究了以常压低功率氩微波诱导等离子体（ＭＩＰ）为原子化器的原子吸收光谱法（ＡＡＳ）测定银和镉。采用电热蒸发（ＥＴＶ）,浓Ｈ２ＳＯ４吸收去溶的进样方法。考察了微波前向功率,载气流量,去溶电压,去溶时间,蒸发电压,酸度对银,镉测定的影响。方法已用于试样分析。     

亲和毛细管电泳激光诱导荧光法测定牛血清白蛋白与其单克隆抗体的结合常数

生物分子之间的特异性相互作用是生物界普遍存在的现象．研究这些现象,对揭示生物化学作用机理、药物研究等具有重要意义．结合常数Ｋｂ是描述生物分子之间特异性相互作用最主要的参数,测定结合常数的传统方法包括平衡透析、凝胶过滤色谱和分光光度法等［１］．亲和毛细管电泳（Ａｆｆｉｎｉｔｙｃａｐｉｌｌａｒｙｅｌｅｃｔｒｏｐｈｏｒｅｓｉｓ,简称ＡＣＥ）是近几年发展起来的毛细管电泳的一个分支,在研究生物分子之间特异性相互作用等方面有很好的应用前景［２～５］．与上述传统方法相比,ＡＣＥ具有测定速度快,样品用量少,有多…     

Stable Marriage and Genetic Algorithms: A Fertile Union

We describe a pair of genetic algorithms for solving two stable matching problems. Both stable matching problems we will consider involve a set of applicants for positions and a set of employers. Each applicant and each employer prepares a rank order list of a subset of the actors in the other set. The goal is to find an assignment of applicants to employers in which if applicant a is not assigned to employer b then either a prefers his assignment to b or b prefers its assignment toa . In other words, no applicant/employer pair can both improve their situations by dropping their current assignments in favor of each other. Our goal will be to enumerate the stable matchings. One of the problems we will consider is the well-known stable marriage problem, in which neither applicant nor employer preference lists are linked. In the other problem, we will allow pairs of applicants who form a couple to submit joint rank order lists of ordered pairs of employers.     

The intermediate regime of light diffraction by ultrasound in planar gyrotropic optical waveguides in an external electric field

A theoretical investigation is carried out for an intermediate regime of optoacoustic interaction, close to the Bragg one, by ultasonic Rayleigh surface waves in gyrotropic planar waveguides in an external electric field. A system of equations of associated waves is presented which describes the planar optoacoustic interaction in intermediate, Raman—Nath, and Bragg regimes of diffraction by ultrasonic surface waves in gyrotropic crystals with electrically induced anisotropy. It is shown that the intermediate (transition) regime of optoacoustic interaction, which is characterized by an angular selectivity and by the presence of several diffraction maxima, is the basic regime of diffraction. In this case diffracted light is generally elliptically polarized with an ellipticity and polarization azimuth that depend on the external electric field intensity. Translated from Zhurrnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 30–35, January–February, 1999.     

X射线荧光光谱分析

评述了我国在2000年7月-2002年6月间X射线荧光光谱，包括粒子激发的X射线光谱的发展和应用，内容包括仪器研制、激发源、探测器、软件、仪器改造、仪器维护和维修、样品制备技术、分析方法研究和应用。     

电子亲合力与诱导效应的定量关系

本文提出了电子亲合力与诱导效应之间的定量关系。通过计算说明了电子亲合力与诱导效应的定量相关比电负性与诱导效应的定量相关好得多；并应用其定量关系式预测尚未实测到的取代基的电子亲合力值；根据计算结果, 可从不同实验方法测得的电子亲合力值中选择正确的实验值。该定量关系式能更加准确和定量地表征出诱导效应的作用。     

微波消解ICP-AES法测定高速工具钢中锰、磷、镍、铜、铬、钒

高速工具钢为高碳高合金工具钢,常温下样品酸溶分解较为困难。本文利用微波消解提高溶样的温度和压力,在王水、氢氟酸和硫酸介质中使样品充分消解,再用饱和硼酸溶液络合过量的氢氟酸,基体匹配消除铁基体的影响,ICP-AES法同时测定锰、磷、镍、铜、铬、钒的含量。测定高速工具钢标样,测定值与标样值相吻合,本方法的精密度在0.55%～4.06%。加标回收率在95.6%～114.8%,满足测定要求。     

光诱导转化法制备单晶Ag纳米三棱体和立方体

The preparation of Ag nanoparticles with the non-spherical shape has been conducted from aqueous solution by photo induced conversion. Ag nanoprisms (80～120nm) and nanocube s(90～200nm) were respectively obtained in the presence of trisodiumcitrate (TSC) orpolyvinylpirrolidon (PVP). These Ag nanoparticles were single-crystals. The results showed that Ag nanoprisms had apreferential growth direction along the Ag(111) axis and Ag nanocubes had a preferential growth direction along the Ag(100) axis. By means of characterization with TEM, ED and UV-V is Spectra, the fundamental analyses and discussion about the changing causes of nanoparticles shape from spherical tonon-spherical have been carried out in the photo induced process.     

On weights of induced paths and cycles in claw‐free and K1,r‐free graphs

Let G be a K_1,r ‐free graph (r ≥ 3) on n vertices. We prove that, for any induced path or induced cycle on k vertices in G (k ≥ 2r − 1 or k ≥ 2r, respectively), the degree sum of its vertices is at most (2r − 2)(n − α) where α is the independence number of G. As a corollary we obtain an upper bound on the length of a longest induced path and a longest induced cycle in a K_1,r ‐free graph. Stronger bounds are given in the special case of claw‐free graphs (i.e., r = 3). Sharpness examples are also presented. © 2001 John Wiley & Sons, Inc. J Graph Theory 36: 131–143, 2001     

Induced chiral helical effect on the main chain of aliphatic polyacetylenes

11‐Dodecyn‐1‐ol as an achiral, aliphatic, monosubstituted acetylene was copolymerized with cholesteryl 3‐butynyl carbonate as a chiral, aliphatic, monosubstituted acetylene with Rh(nbd)[B(C₆H₅)₄] (nbd = norbornadiene) in tetrahydrofuran. The main chain of the obtained copolymers seemed to be mainly composed of the cis‐type structure. The backbone π–π* transition of these copolymers showed significant circular dichroism (CD), indicating an excess of one‐handed helical conformation. These CD signals were varied with the contents of the cholesteryl units in the copolymers. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 913–917, 2001